TFSI产业化 之 LiTFSI及TFSI-ILs性质、应用汇总

2019-11-18 20:31:57 adman 128

LiTFSI     [量产]        

Li-TFSI

双三氟甲磺酰亚胺锂 

CAS:90076-65-6

粉体、水溶、易吸潮

LiTFSI.jpg

TFSI-ILsTFSI离子液体)[量产]

EMI-TFSI

1-乙基-3-甲基咪唑双三氟甲磺酰亚胺盐

 CAS:174899-82-2

无色透明液体、疏水

EMI-TFSI.png
BMI-TFSI

1-丁基-3-甲基咪唑双三氟甲磺酰亚胺盐

CAS:174899-83-3

无色透明液体、疏水

BMI-TFSI.png
TBMA-TFSI 

三丁基甲基铵双三氟甲磺酰亚胺盐

CAS:405514-94-5

无色透明液体(>28℃)、疏水

TBMA-TFSI.jpg


性质、应用


  1. 抗静电(添加剂)

    高透光性,ppm级添加量即可显著降低表面电阻,显著提升亚克力、PU、PC等树酯或胶粘剂抗静电性能

    (1) Antistatic effects of ionic liquids for polyether-based polyurethanes, Electrochimica Acta, Volume 175, 1 September 2015, Pages 13-17 

    (2) Bis(trifluoromethanesulfonyl)imide‐Type Ionic Liquids as Excellent Antistatic Agents for Polyurethanes, Macromol. Mater. Eng., 2014, 299, 794-798

    (3) Fixation of ionic liquids into polyether-based polyurethane films to maintain long-term antistatic properties,  Polymer, Volume 55, Issue 10, 13 May 2014, Pages 2501-2504

    (4) Investigations on the interactions between Li-TFSI and glass fibers in the ternary PP/GF/Li-TFSI composites, Chinese Journal of Polymer Science, January 2018, Volume 36, Issue 1, pp 113–118

    (5) Glass-Fiber Networks as an Orbit for Ions: Fabrication of Excellent Antistatic PP/GF Composites with Extremely Low Organic Salt LoadingsACS Appl. Mater. Interfaces 2017, 9, 18305−18313


  2. 离子凝胶、膜

    (1) Versatile Supramolecular Gelators That Can Harden Water, Organic Solvents and Ionic Liquids,  dx.doi.org/10.1021/la301442f| Langmuir 2012, 28, 9259−9266

    2.1 电致变色

    (1) Flexible and Transparent Electrochromic Displays with Simultaneously Implementable Subpixelated Ion Gel‐Based Viologens by Multiple Patterning, Adv. Funct. Mater. 2019, 29, 1808911

    2.2 磁电调控

    (1) Low-Voltage Control of (Co/Pt)x Perpendicular Magnetic Anisotropy Heterostructure for Flexible Spintronics, ACS Nano 2018 12 (7), 7167-7173

    2.3 电解质

    (1) Ion Gels Prepared by in Situ Radical Polymerization of Vinyl Monomers in an Ionic Liquid and Their Characterization as Polymer Electrolytes, J. AM. CHEM. SOC. 9 VOL. 127, NO. 13, 2005 4977

    (2) Non-volatile, Li-doped ion gel electrolytes for flexible WO3-based electrochromic devices, Materials & Design, Volume 162, 15 January 2019, Pages 45-51

    2.4 自组装

    (1) Effects of Cooling Rates on Self-Assembling Structures of 12-Hydroxystearic Acid in an Ionic LiquidAdvances in Materials Science and Engineering, Volume 2017, Article ID 4762379, 8 pages

    2.5 导电膜

    (1) Effect of Confinement on Proton Transport Mechanisms in Block Copolymer/Ionic Liquid Membranes, Macromolecules 2012, 45, 3112−3120

    image.png


  3. 润滑(添加剂)

    (1) Dramatically improved friction reduction and wear resistance by in situ formed ionic liquids, Received 9th May 2012, Accepted 14th May 2012


  4. 吸收(吸收剂)、萃取(萃取剂)

    4.1 药物残留富集

    (1) Developing microwave-assisted ionic liquid microextraction for the detection and tracking of hydrophobic pesticides in complex environmental matrices, RSC Adv., 2013, 3, 17113–17119

    4.2 离子捕集

    (1) Extraction of lithium from salt lake brine using room temperature ionic liquid in tributyl phosphate, Solvent Extraction Research and Development, Japan, Vol. 25, No. 2, 117-123 (2018)

    Graphical abstract: Developing microwave-assisted ionic liquid microextraction for the detection and tracking of hydrophobic pesticides in complex environmental matrices


  5. 催化(催化剂)

    5.1 烷基化反应

    (1) Synthesis of efficient SBA-15 immobilized ionic liquid catalyst and its performance for Friedel–Crafts reactionCatalysis Today, 276 (2016) 112–120

    Monils - 默尼离子液体


  6. 待续...




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标签:   LiTFSI TFSI-ILs TFSI离子液体 双三氟甲磺酰亚胺锂 离子液体抗静电